Before asking could you actually look at your user interface for while please. 
add a custom vector attribute to your particle (if you dont know read the manual, your going to need to anyway start now if you havent yet)
in the isntancer dialogbox (yes you allways need to choose the BOX next to the isntancer menuitem), check allow all datatypes and assign the aim direction to velocity and aim up axis to your vector. Now all you nee dto do is put some values to that vector and rotate it about.